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First synthesis of 6,7-diaminoindole and 1,2,5-selenadiazolo[3,4-g]indole
Södertörn University, Avdelning Naturvetenskap. Karolinska Institute.
Södertörn University, Avdelning Naturvetenskap. Karolinska Institute.
2000 (English)In: ARKIVOC, ISSN 1424-6376, no 1, 1-5 p.Article in journal (Refereed) Published
Abstract [en]

5-Methyl-4-nitro-2,1,3-benzoselenadiazole (1) was converted into 1,2,5-selenadiazolo[3,4-g]indole (3) by the Batcho-Leimgruber indole synthesis. Subsequent deselenation afforded 6,7-diaminoindole (4) which on treatment with biacetyl afforded 2,3-dimethylpyrrolo[2,3-f]quinoxaline (5) in 80% yield from 3.

Place, publisher, year, edition, pages
2000. no 1, 1-5 p.
Keyword [en]
1, 2, 5 selenadiazolo[3, 4 g]indole, 2, 3 butanedione, 2, 3 dimethylpyrrolo[2, 3 f]quinoxaline, 5 methyl 4 nitro 2, 1, 3 benzoselenadiazole, 6, 7 diaminoindole, indole derivative, quinoxaline derivative, sulfadiazine, unclassified drug, article, synthesis
National Category
Biological Sciences
Identifiers
URN: urn:nbn:se:sh:diva-22244ScopusID: 2-s2.0-3042704941OAI: oai:DiVA.org:sh-22244DiVA: diva2:697578
Available from: 2014-02-18 Created: 2014-02-14 Last updated: 2014-02-18Bibliographically approved

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