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Coupling reactions of indole-3-acetic acid derivatives. Synthesis of arcyriaflavin A
Södertörn University, Avdelning Naturvetenskap.
2000 (English)In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, ISSN 1470-4358, no 16, 2609-2614 p.Article in journal (Refereed) Published
Abstract [en]

The bisindolesuccinic acid methyl ester 10 was obtained by an iodine-promoted coupling of the dianion 9. The diester was converted to the N-benzylimide 12, which was oxidatively cyclized to the indolo[2,3-a]pyrrolo[3,4-c]carbazole 15. The diester 10 could be directly transformed to the known indolocarbazole diester 27 via acid-induced intramolecular cyclization in TFA. The same methodology gave arcyriaflavin A 4 from the succinimide 18b.

Place, publisher, year, edition, pages
2000. no 16, 2609-2614 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:sh:diva-15765DOI: 10.1039/b004029kISI: 000088767000009OAI: oai:DiVA.org:sh-15765DiVA: diva2:508027
Available from: 2012-03-07 Created: 2012-03-07 Last updated: 2012-03-07Bibliographically approved

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Bergman, Jan
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Avdelning Naturvetenskap
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