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Synthesis of barettin
Södertörn University, School of Chemistry, Biology, Geography and Environmental Science. Karolinska Institute.
Södertörn University, School of Chemistry, Biology, Geography and Environmental Science. Karolinska Institute.
2004 (English)In: Tetrahedron, ISSN 0040-4020, E-ISSN 1464-5416, Vol. 60, no 4, 961-965 p.Article in journal (Refereed) Published
Abstract [en]

The indole alkaloid barettin (with bromine in 6-position), isolated from the marine sponge Geodia Barretti, has been synthesised via a Horner-Wadsworth-Emmons type reaction from 6-bromoindole-3-carboxaldehyde to introduce the dehydro-functionality. Subsequent deprotection and cyclisation afforded the natural product in Z-conformation.

Place, publisher, year, edition, pages
2004. Vol. 60, no 4, 961-965 p.
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:sh:diva-15498DOI: 10.1016/j.tet.2003.11.031ISI: 000188227400018ScopusID: 2-s2.0-0347600586OAI: oai:DiVA.org:sh-15498DiVA: diva2:504350
Available from: 2012-02-20 Created: 2012-02-20 Last updated: 2014-04-17Bibliographically approved

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