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New routes to 3-(Arylthio)indoles: Application to the synthesis of the 3,3 '-bis(indolyl) sulfone core of the marine alkaloid echinosulfone A
Södertörn University, School of Life Sciences.
2006 (English)In: Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, ISSN 0936-5214, E-ISSN 1437-2096, no 15, 2459-2463 p.Article in journal (Refereed) Published
Abstract [en]

A new approach to 3-(arylthio)indoles and related compounds has been developed, based on the reactions of aryl Grignard reagents or lithiated heteroaroinatics with a phenylsulfonyl-protected 3,3'-bis(indolyl) disulfide. In addition, a rational approach to the 3,3'-bis(indolyl) sulfone core of the alkaloid echinosulfone A has been accomplished, involving treatment of a 3-lithioindole with bis(phenylsulfonyl) sulfide as the key step.

Place, publisher, year, edition, pages
2006. no 15, 2459-2463 p.
National Category
Organic Chemistry
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URN: urn:nbn:se:sh:diva-14280DOI: 10.1055/s-2006-950427ISI: 000241175500023ScopusID: 2-s2.0-33749337272OAI: oai:DiVA.org:sh-14280DiVA: diva2:468691
Available from: 2011-12-21 Created: 2011-12-20 Last updated: 2014-03-27Bibliographically approved

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Bergman, Jan
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