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Synthesis of 4-oxo-4,5-dihydro-3H-pyrrolo[2,3-c]quinoline-1-carboxylic acid ethyl ester and its isomer 1-oxo-2,9-dihydro-1H-beta-carboline-4-carboxylic acid ethyl ester
Södertörns högskola, Avdelning Naturvetenskap.
2002 (engelsk)Inngår i: Tetrahedron, ISSN 0040-4020, E-ISSN 1464-5416, Vol. 58, nr 45, s. 9179-9185Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

4-Oxo-4,5-dihydro-3H-pyrrolo[2,3-c]quinoline-1-carboxylic acid ethyl ester was obtained when TosMIC was reacted with 3-methylene-oxindole acetic acid ethyl ester. An alternative synthesis to this pyrroloquinolone was performed via a reduction of a 2,3,4-trisubstituted pyrrole obtained in turn by treatment of a vinyl sulfone with ethyl isocyanoacetate under basic conditions. A beta-carboline, isomeric with the pyrroloquinolone, was synthesised utilizing a tosylimine.

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2002. Vol. 58, nr 45, s. 9179-9185
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URN: urn:nbn:se:sh:diva-15775DOI: 10.1016/S0040-4020(02)01197-3ISI: 000179069000004OAI: oai:DiVA.org:sh-15775DiVA, id: diva2:508329
Tilgjengelig fra: 2012-03-08 Laget: 2012-03-07 Sist oppdatert: 2017-12-07bibliografisk kontrollert

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