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Coupling reactions of indole-3-acetic acid derivatives. Synthesis of arcyriaflavin A
Södertörns högskola, Avdelning Naturvetenskap.
2000 (engelsk)Inngår i: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, ISSN 1470-4358, nr 16, s. 2609-2614Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The bisindolesuccinic acid methyl ester 10 was obtained by an iodine-promoted coupling of the dianion 9. The diester was converted to the N-benzylimide 12, which was oxidatively cyclized to the indolo[2,3-a]pyrrolo[3,4-c]carbazole 15. The diester 10 could be directly transformed to the known indolocarbazole diester 27 via acid-induced intramolecular cyclization in TFA. The same methodology gave arcyriaflavin A 4 from the succinimide 18b.

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2000. nr 16, s. 2609-2614
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URN: urn:nbn:se:sh:diva-15765DOI: 10.1039/b004029kISI: 000088767000009OAI: oai:DiVA.org:sh-15765DiVA, id: diva2:508027
Tilgjengelig fra: 2012-03-07 Laget: 2012-03-07 Sist oppdatert: 2012-03-07bibliografisk kontrollert

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